Experimental Researches in Electricity, Volume 1 20 – Faraday · Library Across
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Experimental Researches in Electricity, Volume 1 20Experimental Researches in Electricity, Volume 1 (part 20)
18
Literature · Science
Experimental Researches in Electricity, Volume 1 20
Experimental Researches in Electricity, Volume 1 (part 20)
FaradayEnglish
1531. In rarefied air the negative glow can easily be obtained. If the rounded ends of two metal rods, about O.2 of an inch in diameter, are introduced into a globe or jar (the air within being rarefied), and being opposite to each other, are about four inches apart, the glow can be obtained on both rods, covering not only the ends, but an inch or two of the part behind. On using balls in the air-pump jar, and adjusting the distance and exhaustion, the negative ball could be covered with glow, whether it were the inductric or the inducteous surface.
1532. When rods are used it is necessary to be aware that, if placed concentrically in the jar or globe, the light on one rod is often reflected by the sides of the vessel on to the other rod, and makes it apparently luminous, when really it is not so. This effect may be detected by shifting the eye at the time of observation, or avoided by using blackened rods.
1533. It is curious to observe the relation of glow, brush, and spark to each other, as produced by positive or negative surfaces; thus, beginning with spark discharge, it passes into brush much sooner when the surface at which the discharge commences (1484.) is negative, than it does when positive; but proceeding onwards in the order of change, we find that the positive brush passes into glow long before the negative brush does. So that, though each presents the three conditions in the same general order, the series are not precisely the same. It is probable, that, when these points are minutely examined, as they must be shortly, we shall find that each different gas or dielectric presents its own peculiar results, dependent upon the mode in which its particles assume polar electric condition.
1534. The glow occurs in all gases in which I have looked for it. These are air, nitrogen, oxygen, hydrogen, coal gas, carbonic acid, muriatic acid, sulphurous acid and ammonia. I thought also that I obtained it in oil of turpentine, but if so it was very dull and small.
1535. The glow is always accompanied by a wind proceeding either directly out from the glowing part, or directly towards it; the former being the most general case. This takes place even when the glow occurs upon a ball of considerable size: and if matters be so arranged that the ready and regular access of air to a part exhibiting the glow be interfered with or prevented, the glow then disappears.
1536. I have never been able to analyse or separate the glow into visible elementary intermitting discharges (1427. 1433.), nor to obtain the other evidence of intermitting action, namely an audible sound (1431.). The want of success, as respects trials made by ocular means, may depend upon the large size of the glow preventing the separation of the visible images: and, indeed, if it does intermit, it is not likely that all parts intermit at once with a simultaneous regularity.
1537. All the effects tend to show, that glow is due to a continuous charge or discharge of air; in the former case being accompanied by a current from, and in the latter by one to, the place of the glow. As the surrounding air comes up to the charged conductor, on attaining that spot at which the tension of the particles is raised to the sufficient degree (1370. 1410.), it becomes charged, and then moves off, by the joint action of the forces to which it is subject; and, at the same time that it makes way for other particles to come and be charged in turn, actually helps to form that current by which they are brought into the necessary position. Thus, through the regularity of the forces, a constant and quiet result is produced; and that result is, the charging of successive portions of air, the production of a current, and of a continuous glow.
1538. I have frequently been able to make the termination of a rod, which, when left to itself, would produce a brush, produce in preference a glow, simply by aiding the formation of a current of air at its extremity; and, on the other hand, it is not at all difficult to convert the glow into brushes, by affecting the current of air (1574. 1579.) or the inductive action near it.
1539. The transition from glow, on the one hand, to brush and spark, on the other, and, therefore, their connexion, may be established in various ways. Those circumstances which tend to facilitate the charge of the air by the excited conductor, and also those which tend to keep the tension at the same degree notwithstanding the discharge, assist in producing the glow; whereas those which tend to resist the charge of the air or other dielectric, and those which favour the accumulation of electric force prior to discharge, which, sinking by that act, has to be exalted before the tension can again acquire the requisite degree, favour intermitting discharge, and, therefore, the production of brush or spark. Thus, rarefaction of the air, the removal of large conducting surfaces from the neighbourhood of the glowing termination, the presentation of a sharp point towards it, help to sustain or produce the glow: but the condensation of the air, the presentation of the hand or other large surface, the gradual approximation of a discharging ball, tend to convert the glow into brush or even spark. All these circumstances may be traced and reduced, in a manner easily comprehensible, to their relative power of assisting to produce, either a continuous discharge to the air, which gives the glow; or an interrupted one, which produces the brush, and, in a more exalted condition, the spark.
1540. The rounded end of a brass rod, 0.3 of an inch in diameter, was covered with a positive glow by the working of an electrical machine: on stopping the machine, so that the charge of the connected conductor should fall, the glow changed for a moment into brushes just before the discharge ceased altogether, illustrating the necessity for a certain high continuous charge, for a certain sized termination. Working the machine so that the intensity should be just low enough to give continual brushes from the end in free air, the approach of a fine point changed these brushes into a glow. Working the machine so that the termination presented a continual glow in free air, the gradual approach of the hand caused the glow to contract at the very end of the wire, then to throw out a luminous point, which, becoming a foot stalk (1426.), finally produced brushes with large ramifications. All these results are in accordance with what is stated above (1539.).
1541. Greasing the end of a rounded wire will immediately make it produce brushes instead of glow. A ball having a blunt point which can be made to project more or less beyond its surface, at pleasure, can be made to produce every gradation from glow, through brush, to spark.
1542. It is also very interesting and instructive to trace the transition from spark to glow, through the intermediate condition of stream, between ends in a vessel containing air more or less rarefied; but I fear to be prolix.
1543. All the effects show, that the glow is in its nature exactly the same as the luminous part of a brush or ramification, namely a charging of air; the only difference being, that the glow has a continuous appearance from the constant renewal of the same action in the same place, whereas the ramification is due to a momentary, independent and intermitting action of the same kind.
Dark discharge.
1544. I will now notice a very remarkable circumstance in the luminous discharge accompanied by negative glow, which may, perhaps, be correctly traced hereafter into discharges of much higher intensity. Two brass rods, 0.3 of an inch in diameter, entering a glass globe on opposite sides, had their ends brought into contact, and the air about them very much rarefied. A discharge of electricity from the machine was then made through them, and whilst that was continued the ends were separated from each other. At the moment of separation a continuous glow came over the end of the negative rod, the positive termination remaining quite dark. As the distance was increased, a purple stream or haze appeared on the end of the positive rod, and proceeded directly outwards towards the negative rod; elongating as the interval was enlarged, but never joining the negative glow, there being always a short dark space between. This space, of about 1/16th or 1/20th of an inch, was apparently invariable in its extent and its position, relative to the negative rod; nor did the negative glow vary. Whether the negative end were inductric or inducteous, the same effect was produced. It was strange to see the positive purple haze diminish or lengthen as the ends were separated, and yet this dark space and the negative glow remain unaltered (fig. 133).
1545. Two balls were then used in a large air-pump receiver, and the air rarefied. The usual transitions in the character of the discharge took place; but whenever the luminous stream, which appears after the spark and the brush have ceased, was itself changed into glow at the balls, the dark space occurred, and that whether the one or the other ball was made inductric, or positive, or negative.
1546. Sometimes when the negative ball was large, the machine in powerful action, and the rarefaction high, the ball would be covered over half its surface with glow, and then, upon a hasty observation, would seem to exhibit no dark space: but this was a deception, arising from the overlapping of the convex termination of the negative glow and the concave termination of the positive stream. More careful observation and experiment have convinced me, that when the negative glow occurs, it never visibly touches the luminous part of the positive discharge, but that the dark space is always there.
1547. This singular separation of the positive and negative discharge, as far as concerns their luminous character, under circumstances which one would have thought very favourable to their coalescence, is probably connected with their differences when in the form of brush, and is perhaps even dependent on the same cause. Further, there is every likelihood that the dark parts which occur in feeble sparks are also connected with these phenomena. To understand them would be very important, for it is quite clear that in many of the experiments, indeed in all that I have quoted, discharge is taking place across the dark part of the dielectric to an extent quite equal to what occurs in the luminous part. This difference in the result would seem to imply a distinction in the modes by which the two electric forces are brought into equilibrium in the respective parts; and looking upon all the phenomena as giving additional proofs, that it is to the condition of the particles of the dielectric we must refer for the principles of induction and discharge, so it would be of great importance if we could know accurately in what the difference of action in the dark and the luminous parts consisted.
See Professor Johnson's experiments. Silliman's Journal, xxv. p. 57.
1548. The dark discharge through air (1552.), which in the case mentioned is very evident (1544.), leads to the inquiry, whether the particles of air are generally capable of effecting discharge from one to another without becoming luminous; and the inquiry is important, because it is connected with that degree of tension which is necessary to originate discharge (1368. 1370.). Discharge between air and conductors without luminous appearances are very common; and non-luminous discharges by carrying currents of air and other fluids (1562. 1595.) are also common enough: but these are not cases in point, for they are not discharges between insulating particles.
1549. An arrangement was made for discharge between two balls (1485.) (fig. 129.) but, in place of connecting the inducteous ball directly with the discharging train, it was put in communication with the inside coating of a Leyden jar, and the discharging train with the outside coating. Then working the machine, it was found that whenever sonorous and luminous discharge occurred at the balls A B, the jar became charged; but that when these did not occur, the jar acquired no charge: and such was the case when small rounded terminations were used in place of the balls, and also in whatever manner they were arranged. Under these circumstances, therefore, discharge even between the air and conductors was always luminous.
1550. But in other cases, the phenomena are such as to make it almost certain, that dark discharge can take place across air. If the rounded end of a metal rod, 0.15 of an inch in diameter, be made to give a good negative brush, the approach of a smaller end or a blunt point opposite to it will, at a certain distance, cause a diminution of the brush, and a glow will appear on the positive inducteous wire, accompanied by a current of air passing from it. Now, as the air is being charged both at the positive and negative surfaces, it seems a reasonable conclusion, that the charged portions meet somewhere in the interval, and there discharge to each other, without producing any luminous phenomena. It is possible, however, that the air electrified positively at the glowing end may travel on towards the negative surface, and actually form that atmosphere into which the visible negative brushes dart, in which case dark discharge need not, of necessity, occur. But I incline to the former opinion, and think, that the diminution in size of the negative brush, as the positive glow comes on to the end of the opposed wire, is in favour of that view.
1551. Using rarefied air as the dielectric, it is very easy to obtain luminous phenomena as brushes, or glow, upon both conducting balls or terminations, whilst the interval is dark, and that, when the action is so momentary that I think we cannot consider currents as effecting discharge across the dark part. Thus if two balls, about an inch in diameter, and 4 or more inches apart, have the air rarefied about them, and are then interposed in the course of discharge, an interrupted or spark current being produced at the machine, each termination may be made to show luminous phenomena, whilst more or less of the interval is quite dark. The discharge will pass as suddenly as a retarded spark (295. 334.), i.e. in an interval of time almost inappreciably small, and in such a case, I think it must have passed across the dark part as true disruptive discharge, and not by convection.
By spark current I mean one passing in a series of spark between the conductor of the machine and the apparatus: by a continuous current one that passes through metallic conductors, and in that respect without interruption at the same place.
1552. Hence I conclude that dark disruptive discharge may occur (1547. 1550.); and also, that, in the luminous brush, the visible ramifications may not show the full extent of the disruptive discharge (1444. 1452.), but that each may have a dark outside, enveloping, as it were, every part through which the discharge extends. It is probable, even, that there are such things as dark discharges analogous in form to the brush and the spark, but not luminous in any part (1445.).
1553. The occurrence of dark discharge in any case shows at how low a tension disruptive discharge may occur (1548,), and indicates that the light of the ultimate brush or spark is in no relation to the intensity required (1368. 1370.). So to speak, the discharge begins in darkness, and the light is a mere consequence of the quantity which, after discharge has commenced, flows to that spot and there finds its most facile passage (1418. 1435.). As an illustration of the growth generally of discharge, I may remark that, in the experiments on the transition in oxygen of the discharge from spark to brush (1518.), every spark was immediately preceded by a short brush.
1554. The phenomena relative to dark discharge in other gases, though differing in certain characters from those in air, confirm the conclusions drawn above. The two rounded terminations (1544.) (fig. 133.), were placed in muriatic acid gas (1445. 1463.) at the pressure of 6.5 inches of mercury, and a continuous machine current of electricity sent through the apparatus: bright sparks occurred until the interval was about or above an inch, when they were replaced by squat brushy intermitting glows upon both terminations, with a dark part between. When the current at the machine was in spark, then each spark caused a discharge across the muriatic acid gas, which, with a certain interval, was bright; with a larger interval, was straight across and flamy, like a very exhausted and sudden, but not a dense sharp spark; and with a still larger interval, produced a feeble brush on the inductric positive end, and a glow on the inducteous negative end, the dark part being between (1544.); and at such times, the spark at the conductor, instead of being sudden and sonorous, was dull and quiet (334.).
1555. On introducing more muriatic acid gas, until the pressure was 29.97 inches, the same terminations gave bright sparks within at small distances; but when they were about an inch or more apart, the discharge was generally with very small brushes and glow, and frequently with no light at all, though electricity had passed through the gas. Whenever the bright spark did pass through the muriatic acid gas at this pressure, it was bright throughout, presenting no dark or dull space.
1556. In coal gas, at common pressures, when the distance was about an inch, the discharge was accompanied by short brushes on the ends, and a dark interval of half an inch or more between them, notwithstanding the discharge had the sharp quick sound of a dull spark, and could not have depended in the dark part on convection (1562.).
1557. This gas presents several curious points in relation to the bright and dark parts of spark discharge. When bright sparks passed between the rod ends 0.3 of an inch in diameter (1544.), very sudden dark parts would occur next to the brightest portions of the spark. Again with these ends and also with balls (1422.), the bright sparks would be sometimes red, sometimes green, and occasionally green and red in different parts of the same spark. Again, in the experiments described (1518.), at certain intervals a very peculiar pale, dull, yet sudden discharge would pass, which, though apparently weak, was very direct in its course, and accompanied by a sharp snapping noise, as if quick in its occurrence.
1558. Hydrogen frequently gave peculiar sparks, one part being bright red, whilst the other was a dull pale gray, or else the whole spark was dull and peculiar.
1559. Nitrogen presents a very remarkable discharge, between two balls of the respective diameters of 0.15 and 2 inches (1506. 1518.), the smaller one being rendered negative either directly inducteously. The peculiar discharge occurs at intervals between 0.42 and 0.68, and even at 1.4 inches when the large ball was inductric positively; it consisted of a little brushy part on the small negative ball, then a dark space, and lastly a dull straight line on the large positive ball (fig. 134.). The position of the dark space was very constant, and is probably in direct relation to the dark space described when negative glow was produced (1544.). When by any circumstance a bright spark was determined, the contrast with the peculiar spark described was very striking; for it always had a faint purple part, but the place of this part was constantly near the positive ball.
1560. Thus dark discharge appears to be decidedly established. But its establishment is accompanied by proofs that it occurs in different degrees and modes in different gases. Hence then another specific action, added to the many (1296. 1398. 1399. 1423. 1454. 1503.) by which the electrical relations of insulating dielectrics are distinguished and established, and another argument in favour of that molecular theory of induction, which is at present under examination.
I cannot resist referring here by a note to Biot's philosophical view of the nature of the light of the electric discharge, Annales de Chimie, liii. p. 321.
1561. What I have had to say regarding disruptive discharge has extended to some length, but I hope will be excused in consequence of the importance of the subject. Before concluding my remarks, I will again intimate in the form of a query, whether we have not reason to consider the tension or retention and after discharge in air or other insulating dielectrics, as the same thing with retardation and discharge in a metal wire, differing only, but almost infinitely, in degree (1334. 1336.). In other words, can we not, by a gradual chain of association, carry up discharge from its occurrence in air, through spermaceti and water, to solutions, and then on to chlorides, oxides and metals, without any essential change in its character; and, at the same time, connecting the insensible conduction of air, through muriatic acid gas and the dark discharge, with the better conduction of spermaceti, water, and the all but perfect conduction of the metals, associate the phenomena at both extremes? and may it not be, that the retardation and ignition of a wire are effects exactly correspondent in their nature to the retention of charge and spark in air? If so, here again the two extremes in property amongst dielectrics will be found to be in intimate relation, the whole difference probably depending upon the mode and degree in which their particles polarize under the influence of inductive actions (1338. 1603. 1610.).
¶ x. Convection, or carrying discharge.
1562. The last kind of discharge which I have to consider is that effected by the motion of charged particles from place to place. It is apparently very different in its nature to any of the former modes of discharge (1319.), but, as the result is the same, may be of great importance in illustrating, not merely the nature of discharge itself, but also of what we call the electric current. It often, as before observed, in cases of brush and glow (1440. 1535.), joins its effect to that of disruptive discharge, to complete the act of neutralization amongst the electric forces.
1563. The particles which being charged, then travel, may be either of insulating or conducting matter, large or small. The consideration in the first place of a large particle of conducting matter may perhaps help our conceptions.
1564. A copper boiler 3 feet in diameter was insulated and electrified, but so feebly, that dissipation by brushes or disruptive discharge did not occur at its edges or projecting parts in a sensible degree. A brass ball, 2 inches in diameter, suspended by a clean white silk thread, was brought towards it, and it was found that, if the ball was held for a second or two near any part of the charged surface of the boiler, at such distance (two inches more or less) as not to receive any direct charge from it, it became itself charged, although insulated the whole time; and its electricity was the reverse of that of the boiler.
1565. This effect was the strongest opposite the edges and projecting parts of the boiler, and weaker opposite the sides, or those extended portions of the surface which, according to Coulomb's results, have the weakest charge. It was very strong opposite a rod projecting a little way from the boiler. It occurred when the copper was charged negatively as well as positively: it was produced also with small balls down to 0.2 of an inch and less in diameter, and also with smaller charged conductors than the copper. It is, indeed, hardly possible in some cases to carry an insulated ball within an inch or two of a charged plane or convex surface without its receiving a charge of the contrary kind to that of the surface.
1566. This effect is one of induction between the bodies, not of communication. The ball, when related to the positive charged surface by the intervening dielectric, has its opposite sides brought into contrary states, that side towards the boiler being negative and the outer side positive. More inductric action is directed towards it than would have passed across the same place if the ball had not been there, for several reasons; amongst others, because, being a conductor, the resistance of the particles of the dielectric, which otherwise would have been there, is removed (1298.); and also, because the reacting positive surface of the ball being projected further out from the boiler than when there is no introduction of conducting matter, is more free therefore to act through the rest of the dielectric towards surrounding conductors, and so favours the exaltation of that inductric polarity which is directed in its course. It is, as to the exaltation of force upon its outer surface beyond that upon the inductric surface of the boiler, as if the latter were itself protuberant in that direction. Thus it acquires a state like, but higher than, that of the surface of the boiler which causes it; and sufficiently exalted to discharge at its positive surface to the air, or to affect small particles, as it is itself affected by the boiler, and they flying to it, take a charge and pass off; and so the ball, as a whole, is brought into the contrary inducteous state. The consequence is, that, if free to move, its tendency, under the influence of all the forces, to approach the boiler is increased, whilst it at the same time becomes more and more exalted in its condition, both of polarity and charge, until, at a certain distance, discharge takes place, it acquires the same state as the boiler, is repelled, and passing to that conductor most favourably circumstanced to discharge it, there resumes its first indifferent condition.
1567. It seems to me, that the manner in which inductric bodies affect uncharged floating or moveable conductors near them, is very frequently of this nature, and generally so when it ends in a carrying operation (1562. 1602.). The manner in which, whilst the dominant inductric body cannot give off its electricity to the air, the inducteous body can effect the discharge of the same kind of force, is curious, and, in the case of elongated or irregularly shaped conductors, such as filaments or particles of dust, the effect will often be very ready, and the consequent attraction immediate.
1568. The effect described is also probably influential in causing those variations in spark discharge referred to in the last series (1386. 1390. 1391.): for if a particle of dust were drawn towards the axis of induction between the balls, it would tend, whilst at some distance from that axis, to commence discharge at itself, in the manner described (1566.), and that commencement might so far facilitate the act (1417. 1420.) as to make the complete discharge, as spark, pass through the particle, though it might not be the shortest course from ball to ball. So also, with equal balls at equal distances, as in the experiments of comparison already described (1493. 1506.), a particle being between one pair of balls would cause discharge there in preference; or even if a particle were between each, difference of size or shape would give one for the time a predominance over the other.
1569. The power of particles of dust to carry off electricity in cases of high tension is well known, and I have already mentioned some instances of the kind in the use of the inductive apparatus (1201.). The general operation is very well shown by large light objects, as the toy called the electrical spider; or, if smaller ones are wanted for philosophical investigation, by the smoke of a glowing green wax taper, which, presenting a successive stream of such particles, makes their course visible.
1570. On using oil of turpentine as the dielectric, the action and course of small conducting carrying particles in it can be well observed. A few short pieces of thread will supply the place of carriers, and their progressive action is exceedingly interesting.
1571. A very striking effect was produced on oil of turpentine, which, whether it was due to the carrying power of the particles in it, or to any other action of them, is perhaps as yet doubtful. A portion of that fluid in a glass vessel had a large uninsulated silver dish at the bottom, and an electrified metal rod with a round termination dipping into it at the top. The insulation was very good, and the attraction and other phenomena striking. The rod end, with a drop of gum water attached to it, was then electrified in the fluid; the gum water soon spun off in fine threads, and was quickly dissipated through the oil of turpentine. By the time that four drops had in this way been commingled with a pint of the dielectric, the latter had lost by far the greatest portion of its insulating power; no sparks could be obtained in the fluid; and all the phenomena dependent upon insulation had sunk to a low degree. The fluid was very slightly turbid. Upon being filtered through paper only, it resumed its first clearness, and now insulated as well as before. The water, therefore, was merely diffused through the oil of turpentine, not combined with or dissolved in it: but whether the minute particles acted as carriers, or whether they were not rather gathered together in the line of highest inductive tension (1350.), and there, being drawn into elongated forms by the electric forces, combined their effects to produce a band of matter having considerable conducting power, as compared with the oil of turpentine, is as yet questionable.
1572. The analogy between the action of solid conducting carrying particles and that of the charged particles of fluid insulating substances, acting as dielectrics, is very evident and simple; but in the latter case the result is, necessarily, currents in the mobile media. Particles are brought by inductric action into a polar state; and the latter, after rising to a certain tension (1370.), is followed by the communication of a part of the force originally on the conductor; the particles consequently become charged, and then, under the joint influence of the repellent and attractive forces, are urged towards a discharging place, or to that spot where these inductric forces are most easily compensated by the contrary inducteous forces.
1573. Why a point should be so exceedingly favourable to the production of currents in a fluid insulating dielectric, as air, is very evident. It is at the extremity of the point that the intensity necessary to charge the air is first acquired (1374.); it is from thence that the charged particle recedes; and the mechanical force which it impresses on the air to form a current is in every way favoured by the shape and position of the rod, of which the point forms the termination. At the same time, the point, having become the origin of an active mechanical force, does, by the very act of causing that force, namely, by discharge, prevent any other part of the rod from acquiring the same necessary condition, and so preserves and sustains its own predominance.
1574. The very varied and beautiful phenomena produced by sheltering or enclosing the point, illustrate the production of the current exceedingly well, and justify the same conclusions; it being remembered that in such cases the effect upon the discharge is of two kinds. For the current may be interfered with by stopping the access of fresh uncharged air, or retarding the removal of that which has been charged, as when a point is electrified in a tube of insulating matter closed at one extremity; or the electric condition of the point itself may be altered by the relation of other parts in its neighbourhood, also rendered electric, as when the point is in a metal tube, by the metal itself, or when it is in the glass tube, by a similar action of the charged parts of the glass, or even by the surrounding air which has been charged, and which cannot escape.
1575. Whenever it is intended to observe such inductive phenomena in a fluid dielectric as have a direct relation to, and dependence upon, the fluidity of the medium, such, for instance, as discharge from points, or attractions and repulsions, &c., then the mass of the fluid should be great, and in such proportion to the distance between the inductric and inducteous surfaces as to include all the lines of inductive force (1369.) between them; otherwise, the effects of currents, attraction, &c., which are the resultants of all these forces, cannot be obtained. The phenomena, which occur in the open air, or in the middle of a globe filled with oil of turpentine, will not take place in the same media if confined in tubes of glass, shell-lac, sulphur, or other such substances, though they be excellent insulating dielectrics; nor can they be expected: for in such cases, the polar forces, instead of being all dispersed amongst fluid particles, which tend to move under their influence, are now associated in many parts with particles that, notwithstanding their tendency to motion, are constrained by their solidity to remain quiescent.
1576. The varied circumstances under which, with conductors differently formed and constituted, currents can occur, all illustrate the same simplicity of production. A ball, if the intensity be raised sufficiently on its surface, and that intensity be greatest on a part consistent with the production of a current of air up to and off from it, will produce the effect like a point (1537); such is the case whenever the glow occurs upon a ball, the current being essential to that phenomenon. If as large a sphere as can well be employed with the production of glow be used, the glow will appear at the place where the current leaves the ball, and that will be the part directly opposite to the connection of the ball and rod which supports it; but by increasing the tension elsewhere, so as to raise it above the tension upon that spot, which can easily be effected inductively, then the place of the glow and the direction of the current will also change, and pass to that spot which for the time is most favourable for their production (1591.).
1577. For instance, approaching the hand towards the ball will tend to cause brush (1539.), but by increasing the supply of electricity the condition of glow may be preserved; then on moving the hand about from side to side the position of the glow will very evidently move with it.
1578. A point brought towards a glowing ball would at twelve or fourteen inches distance make the glow break into brush, but when still nearer, glow was reproduced, probably dependent upon the discharge of wind or air passing from the point to the ball, and this glow was very obedient to the motion of the point, following it in every direction.
1579. Even a current of wind could affect the place of the glow; for a varnished glass tube being directed sideways towards the ball, air was sometimes blown through it at the ball and sometimes not. In the former case, the place of the glow was changed a little, as if it were blown away by the current, and this is just the result which might have been anticipated. All these effects illustrate beautifully the general causes and relations, both of the glow and the current of air accompanying it (1574.).
1580. Flame facilitates the production of a current in the dielectric surrounding it. Thus, if a ball which would not occasion a current in the air have a flame, whether large or small, formed on its surface, the current is produced with the greatest ease; but not the least difficulty can occur in comprehending the effective action of the flame in this case, if its relation, as part of the surrounding dielectric, to the electrified ball, be but for a moment considered (1375. 1380.).
1581. Conducting fluid terminations, instead of rigid points, illustrate in a very beautiful manner the formation of the currents, with their effects and influence in exalting the conditions under which they were commenced. Let the rounded end of a brass rod, 0.3 of an inch or thereabouts in diameter, point downwards in free air; let it be amalgamated, and have a drop of mercury suspended from it; and then let it be powerfully electrized. The mercury will present the phenomenon of glow; a current of air will rush along the rod, and set off from the mercury directly downwards; and the form of the metallic drop will be slightly affected, the convexity at a small part near the middle and lower part becoming greater, whilst it diminishes all round at places a little removed from this spot. The change is from the form of a (fig. 135.) to that of b, and is due almost, if not entirely, to the mechanical force of the current of air sweeping over its surface.
1582. As a comparative observation, let it be noticed, that a ball gradually brought towards it converts the glow into brushes, and ultimately sparks pass from the most projecting part of the mercury. A point does the same, but at much smaller distances.
1583. Take next a drop of strong solution of muriate of lime; being electrified, a part will probably be dissipated, but a considerable portion, if the electricity be not too powerful, will remain, forming a conical drop (fig. 136.), accompanied by a strong current. If glow be produced, the drop will be smooth on the surface. If a short low brush is formed, a minute tremulous motion of the liquid will be visible; but both effects coincide with the principal one to be observed, namely, the regular and successive charge of air, the formation of a wind or current, and the form given by that current to the fluid drop, if a discharge ball be gradually brought toward the cone, sparks will at last pass, and these will be from the apex of the cone to the approached ball, indicating a considerable degree of conducting power in this fluid.
1584. With a drop of water, the effects were of the same kind, and were best obtained when a portion of gum water or of syrup hung from a ball (fig. 137.). When the machine was worked slowly, a fine large quiet conical drop, with concave lateral outline, and a small rounded end, was produced, on which the glow appeared, whilst a steady wind issued, in a direction from the point of the cone, of sufficient force to depress the surface of uninsulated water held opposite to the termination. When the machine was worked more rapidly some of the water was driven off; the smaller pointed portion left was roughish on the surface, and the sound of successive brush discharges was heard. With still more electricity, more water was dispersed; that which remained was elongated and contracted, with an alternating motion; a stronger brush discharge was heard, and the vibrations of the water and the successive discharges of the individual brushes were simultaneous. When water from beneath was brought towards the drop, it did not indicate the same regular strong contracted current of air as before; and when the distance was such that sparks passed, the water beneath was attracted rather than driven away, and the current of air ceased.
1585. When the discharging ball was brought near the drop in its first quiet glowing state (1582.), it converted that glow into brushes, and caused the vibrating motion of the drop. When still nearer, sparks passed, but they were always from the metal of the rod, over the surface of the water, to the point, and then across the air to the ball. This is a natural consequence of the deficient conducting power of the fluid (1584. 1585.).
1586. Why the drop vibrated, changing its form between the periods of discharging brushes, so as to be more or less acute at particular instants, to be most acute when the brush issued forth, and to be isochronous in its action, and how the quiet glowing liquid drop, on assuming the conical form, facilitated, as it were, the first action, are points, as to theory, so evident, that I will not stop to speak of them. The principal thing to observe at present is, the formation of the carrying current of air, and the manner in which it exhibits its existence and influence by giving form to the drop.
1587. That the drop, when of water, or a better conductor than water, is formed into a cone principally by the current of air, is shown amongst other ways (1594.) thus. A sharp point being held opposite the conical drop, the latter soon lost its pointed form; was retraced and became round; the current of air from it ceased, and was replaced by one from the point beneath, which, if the latter were held near enough to the drop, actually blew it aside, and rendered it concave in form.
1588. It is hardly necessary to say what happened with still worse conductors than water, as oil, or oil of turpentine; the fluid itself was then spun out into threads and carried off, not only because the air rushing over its surface helped to sweep it away, but also because its insulating particles assumed the same charged state as the particles of air, and, not being able to discharge to them in a much greater decree than the air particles themselves could do, were carried off by the same causes which urged those in their course. A similar effect with melted sealing-wax on a metal point forms an old and well-known experiment.
1589. A drop of gum water in the exhausted receiver of the air-pump was not sensibly affected in its form when electrified. When air was let in, it begun to show change of shape when the pressure was ten inches of mercury. At the pressure of fourteen or fifteen inches the change was more sensible, and as the air increased in density the effects increased, until they were the same as those in the open atmosphere. The diminished effect in the rare air I refer to the relative diminished energy of its current; that diminution depending, in the first place, on the lower electric condition of the electrified ball in the rarefied medium, and in the next, on the attenuated condition of the dielectric, the cohesive force of water in relation to rarefied air being something like that of mercury to dense air (1581.), whilst that of water in dense air may be compared to that of mercury in oil of turpentine (1597.).
1590. When a ball is covered with a thick conducting fluid, as treacle or syrup, it is easy by inductive action to determine the wind from almost any part of it (1577.); the experiment, which before was of rather difficult performance, being rendered facile in consequence of the fluid enabling that part, which at first was feeble in its action, to rise into an exalted condition by assuming a pointed form.
1591. To produce the current, the electric intensity must rise and continue at one spot, namely, at the origin of the current, higher than elsewhere, and then, air having a uniform and ready access, the current is produced. If no current be allowed (1574.), then discharge may take place by brush or spark. But whether it be by brush or spark, or wind, it seems very probable that the initial intensity or tension at which a particle of a given gaseous dielectric charges, or commences discharge, is, under the conditions before expressed, always the same (1410.).
1592. It is not supposed that all the air which enters into motion is electrified; on the contrary, much that is not charged is carried on into the stream. The part which is really charged may be but a small proportion of that which is ultimately set in motion (1442.).
1593. When a drop of gum water (1584.) is made negative, it presents a larger cone than when made positive; less of the fluid is thrown off, and yet, when a ball is approached, sparks can hardly be obtained, so pointed is the cone, and so free the discharge. A point held opposite to it did not cause the retraction of the cone to such an extent as when it was positive. All the effects are so different from those presented by the positive cone, that I have no doubt such drops would present a very instructive method of investigating the difference of positive and negative discharge in air and other dielectrics (1480. 1501.).
1594. That I may not be misunderstood (1587.), I must observe here that I do not consider the cones produced as the result only of the current of air or other insulating dielectric over their surface. When the drop is of badly conducting matter, a part of the effect is due to the electrified state of the particles, and this part constitutes almost the whole when the matter is melted sealing-wax, oil of turpentine, and similar insulating bodies (1588.). But even when the drop is of good conducting matter, as water, solutions, or mercury, though the effect above spoken of will then be insensible (1607.), still it is not the mere current of air or other dielectric which produces all the change of form; for a part is due to those attractive forces by which the charged drop, if free to move, would travel along the line of strongest induction, and not being free to move, has its form elongated until the sum of the different forces tending to produce this form is balanced by the cohesive attraction of the fluid. The effect of the attractive forces are well shown when treacle, gum water, or syrup is used; for the long threads which spin out, at the same time that they form the axes of the currents of air, which may still be considered as determined at their points, are like flexible conductors, and show by their directions in what way the attractive forces draw them.
1595. When the phenomena of currents are observed in dense insulating dielectrics, they present us with extraordinary degrees of mechanical force. Thus, if a pint of well-rectified and filtered (1571.) oil of turpentine be put into a glass vessel, and two wires be dipped into it in different places, one leading to the electrical machine, and the other to the discharging train, on working the machine the fluid will be thrown into violent motion throughout its whole mass, whilst at the same time it will rise two, three or four inches up the machine wire, and dart off jets from it into the air.
1596. If very clean uninsulated mercury be at the bottom of the fluid, and the wire from the machine be terminated either by a ball or a point, and also pass through a glass tube extending both above and below the surface of the oil of turpentine, the currents can be better observed, and will be seen to rush down the wire, proceeding directly from it towards the mercury, and there, diverging in all directions, will ripple its surface strongly, and mounting up at the sides of the vessel, will return to re-enter upon their course.
1597. A drop of mercury being suspended from an amalgamated brass ball, preserved its form almost unchanged in air (1581.); but when immersed in the oil of turpentine it became very pointed, and even particles of the metal could be spun out and carried off by the currents of the dielectric. The form of the liquid metal was just like that of the syrup in air (1584.), the point of the cone being quite as fine, though not so long. By bringing a sharp uninsulated point towards it, it could also be effected in the same manner as the syrup drop in air (1587.), though not so readily, because of the density and limited quantity of the dielectric.
1598. If the mercury at the bottom of the fluid be connected with the electrical machine, whilst a rod is held in the hand terminating in a ball three quarters of an inch, less or more, in diameter, and the ball be dipped into the electrified fluid, very striking appearances ensue. When the ball is raised again so as to be at a level nearly out of the fluid, large portions of the latter will seem to cling to it (fig. 138.). If it be raised higher, a column of the oil of turpentine will still connect it with that in the basin below (fig. 139.). If the machine be excited into more powerful action, this will become more bulky, and may then also be raised higher, assuming the form (fig. 140); and all the time that these effects continue, currents and counter-currents, sometimes running very close together, may be observed in the raised column of fluid.
1599. It is very difficult to decide by sight the direction of the currents in such experiments as these. If particles of silk are introduced they cling about the conductors; but using drops of water and mercury the course of the fluid dielectric seems well indicated. Thus, if a drop of water be placed at the end of a rod (1571.) over the uninsulated mercury, it is soon swept away in particles streaming downwards towards the mercury. If another drop be placed on the mercury beneath the end of the rod, it is quickly dispersed in all directions in the form of streaming particles, the attractive forces drawing it into elongated portions, and the currents carrying them away. If a drop of mercury be hung from a ball used to raise a column of the fluid (1598.), then the shape of the drop seems to show currents travelling in the fluid in the direction indicated by the arrows (fig. 141.).
1600. A very remarkable effect is produced on these phenomena, connected with positive and negative charge and discharge, namely, that a ball charged positively raises a much higher and larger column of the oil of turpentine than when charged negatively. There can be no doubt that this is connected with the difference of positive and negative action already spoken of (1480. 1525.), and tends much to strengthen the idea that such difference is referable to the particles of the dielectric rather than to the charged conductors, and is dependent upon the mode in which these particles polarize (1503. 1523.).
1601. Whenever currents travel in insulating dielectrics they really effect discharge; and it is important to observe, though a very natural result, that it is indifferent which way the current or particles travel, as with reversed direction their state is reversed. The change is easily made, either in air or oil of turpentine, between two opposed rods, for an insulated ball being placed in connexion with either rod and brought near its extremity, will cause the current to set towards it from the opposite end.
1602. The two currents often occur at once, as when both terminations present brushes, and frequently when they exhibit the glow (1531.). In such cases, the charged particles, or many of them, meet and mutually discharge each other (1518. 1612.). If a smoking wax taper be held at the end of an insulating rod towards a charged prime conductor, it will very often happen that two currents will form, and be rendered visible by its vapour, one passing as a fine filament of smoky particles directly to the charged conductor, and the other passing as directly from the same taper wick outwards, and from the conductor: the principles of inductric action and charge, which were referred to in considering the relation of a carrier ball and a conductor (1566.), being here also called into play.
1603. The general analogy and, I think I may say, identity of action found to exist as to insulation and conduction (1338. 1561.) when bodies, the best and the worst in the classes of insulators or conductors, were compared, led me to believe that the phenomena of convection in badly conducting media were not without their parallel amongst the best conductors, such even as the metals. Upon consideration, the cones produced by Davy in fluid metals, as mercury and tin, seemed to be cases in point, and probably also the elongation of the metallic medium through which a current of electricity was passing, described by Ampère (1113); for it is not difficult to conceive, that the diminution of convective effect, consequent upon the high conducting power of the metallic media used in these experiments, might be fully compensated for by the enormous quantity of electricity passing. In fact, it is impossible not to expect some effect, whether sensible or not, of the kind in question, when such a current is passing through a fluid offering a sensible resistance to the passage of the electricity, and, thereby, giving proof of a certain degree of insulating power (1328.).
Philosophical Transactions, 1823, p. 155.
Bibliothèque Universelle, xxi, 417.
1604. I endeavoured to connect the convective currents in air, oil of turpentine, &c. and those in metals, by intermediate cases, but found this not easy to do. On taking bodies, for instance, which, like water, adds, solutions, fused salts or chlorides, &c., have intermediate conducting powers, the minute quantity of electricity which the common machine can supply (371. 861.) is exhausted instantly, so that the cause of the phenomenon is kept either very low in intensity, or the instant of time during which the effect lasts is so small, that one cannot hope to observe the result sought for. If a voltaic battery be used, these bodies are all electrolytes, and the evolution of gas, or the production of other changes, interferes and prevents observation of the effect required.
1605. There are, nevertheless, some experiments which illustrate the connection. Two platina wires, forming the electrodes of a powerful voltaic battery, were placed side by side, near each other, in distilled water, hermetically sealed up in a strong glass tube, some minute vegetable fibres being present in the water. When, from the evolution of gas and the consequent increased pressure, the bubbles formed on the electrodes were so small as to produce but feebly ascending currents, then it could be observed that the filaments present were attracted and repelled between the two wires, as they would have been between two oppositely charged surfaces in air or oil of turpentine, moving so quickly as to displace and disturb the bubbles and the currents which these tended to form. Now I think it cannot be doubted, that under similar circumstances, and with an abundant supply of electricity, of sufficient tension also, convective currents might have been formed; the attractions and repulsions of the filaments were, in fact, the elements of such currents (1572.), and therefore water, though almost infinitely above air or oil of turpentine as a conductor, is a medium in which similar currents can take place.
1606. I had an apparatus made (fig. 142.) in which a is a plate of shell-lac, b a fine platina wire passing through it, and having only the section of the wire exposed above; c a ring of bibulous paper resting on the shell-lac, and d distilled water retained by the paper in its place, and just sufficient in quantity to cover the end of the wire b; another wire, e, touched a piece of tinfoil lying in the water, and was also connected with a discharging train; in this way it was easy, by rendering b either positive or negative, to send a current of electricity by its extremity into the fluid, and so away by the wire e.
1607. On connecting b with the conductor of a powerful electrical machine, not the least disturbance of the level of the fluid over the end of the wire during the working of the machine could be observed; but at the same time there was not the smallest indication of electrical charge about the conductor of the machine, so complete was the discharge. I conclude that the quantity of electricity passed in a given time had been too small, when compared with the conducting power of the fluid to produce the desired effect.
1608. I then charged a large Leyden battery (291.), and discharged it through the wire b, interposing, however, a wet thread, two feet long, to prevent a spark in the water, and to reduce what would else have been a sudden violent discharge into one of more moderate character, enduring for a sensible length of time (334.). I now did obtain a very brief elevation of the water over the end of the wire; and though a few minute bubbles of gas were at the same time formed there, so as to prevent me from asserting that the effect was unequivocally the same as that obtained by DAVY in the metals, yet, according to my best judgement, it was partly, and I believe principally, of that nature.
1609. I employed a voltaic battery of 100 pair of four-inch plates for experiments of a similar nature with electrolytes. In these cases the shell-lac was cupped, and the wire b 0.2 of an inch in diameter. Sometimes I used a positive amalgamated zinc wire in contact with dilute sulphuric acid; at others, a negative copper wire in a solution of sulphate of copper; but, because of the evolution of gas, the precipitation of copper, &c., I was not able to obtain decided results. It is but right to mention, that when I made use of mercury, endeavouring to repeat DAVY's experiment, the battery of 100 pair was not sufficient to produce the elevations.
In the experiments at the Royal Institution, Sir H. Davy used, I think, 500 or 600 pairs of plates. Those at the London Institution were made with the apparatus of Mr. Pepys (consisting of an enormous single pair of plates), described in the Philosophical Transactions for 1832, p. 187.
1610. The latter experiments (1609.) may therefore be considered as failing to give the hoped-for proof, but I have much confidence in the former (1605. 1608.), and in the considerations (1603.) connected with them. If I have rightly viewed them, and we may be allowed to compare the currents at points and surfaces in such extremely different bodies as air and the metals, and admit that they are effects of the same kind, differing only in degree and in proportion to the insulating or conducting power of the dielectric used, what great additional argument we obtain in favour of that theory, which in the phenomena of insulation and conduction also, as in these, would link the same apparently dissimilar substances together (1336. 1561.); and how completely the general view, which refers all the phenomena to the direct action of the molecules of matter, seems to embrace the various isolated phenomena as they successively come under consideration!
1611. The connection of this convective or carrying effect, which depends upon a certain degree of insulation, with conduction; i.e. the occurrence of both in so many of the substances referred to, as, for instance, the metals, water, air, &c., would lead to many very curious theoretical generalizations, which I must not indulge in here. One point, however, I shall venture to refer to. Conduction appears to be essentially an action of contiguous particles, and the considerations just stated, together with others formerly expressed (1326, 1336, &c.), lead to the conclusion, that all bodies conduct, and by the same process, air as well as metals; the only difference being in the necessary degree of force or tension between the particles which must exist before the act of conduction or transfer from one particle to another can take place.
1612. The question then arises, what is this limiting condition which separates, as it were, conduction and insulation from each other? Does it consist in a difference between the two contiguous particles, or the contiguous poles of these particles, in the nature and amount of positive and negative force, no communication or discharge occurring unless that difference rises up to a certain degree, variable for different bodies, but always the same for the same body? Or is it true that, however small the difference between two such particles, if time be allowed, equalization of force will take place, even with the particles of such bodies as air, sulphur or lac? In the first case, insulating power in any particular body would be proportionate to the degree of the assumed necessary difference of force; in the second, to the time required to equalize equal degrees of difference in different bodies. With regard to airs, one is almost led to expect a permanent difference of force; but in all other bodies, time seems to be quite sufficient to ensure, ultimately, complete conduction. The difference in the modes by which insulation may be sustained, or conduction effected, is not a mere fanciful point, but one of great importance, as being essentially connected with the molecular theory of induction, and the manner in which the particles of bodies assume and retain their polarized state.
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Experimental Researches in Electricity, Volume 1 21
